Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides
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چکیده
منابع مشابه
Tetraisopropyldisiloxane-1,3-diyl as a versatile protecting group for pentopyranosides.
The protecting group tetraisopropyldisiloxane-1,3-yl has been investigated for simultaneous protection of two hydroxyls on pentopyranosides. Methyl α-D-xylopyranoside is protected in excellent regioselectivity and high yield to form the 2,3-protected xylopyranoside whereas methyl β-D-xylopyranoside gives the 3,4-protected product also with excellent regioselectivity.
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ژورنال
عنوان ژورنال: Carbohydrate Research
سال: 2012
ISSN: 0008-6215
DOI: 10.1016/j.carres.2012.03.016